論文リスト

72. Alkali Metal Ion Binding Using Cyclic Polyketones
N. Ozawa, K. I. Shivakumar, M. Murugavel, Y. Inaba, T. Yoneda, Y. Ide, J. Pirillo, Y. Hijikata, Y. Inokuma
Chem. Commun. 2022, 58, 2971–2974.
TOC
カルボニルひもの輪がアルカリ金属イオンを包接することを明らかにしました。Chemical Communications HOT Articles 2022に選出されました。
Inside Front Coverに選出されました。
71. Strain-induced Ring Expansion Reactions of Calix[3]pyrrole-related Macrocycles
Y. Inaba, Y. Kakibayashi, Y. Ide, J. Pirillo, Y. Hijikata, T. Yoneda, Y. Inokuma
Chem. Eur. J. 2022, 28, e202200056.
TOC
Calix[3]pyrroleの類縁体を合成して、環拡大反応の適用範囲、反応機構を明らかにしました。
70. Hybrid Eu(III) Coordination luminophore Standing on Silica Nanoparticles by Two Legs for Enhanced Luminescence
T. Zhang, Y. Kitagawa, R. Moriake, P. P. F. Rosa, M. J. Islam, T. Yoneda, Y. Inokuma, K. Fushimi, Y. Hasegawa
Chem. Eur. J. 2021, 27, 14438–14443.
TOC
同学科の長谷川先生との共著論文です。配位子の合成をお手伝いさせて頂きました。
69. Calix[3]pyrrole: A Missing Link in Porphyrin-Related Chemistry
Y. Inaba, Y. Nomata, Y. Ide, J. Pirillo, Y. Hijikata, T. Yoneda, A. Osuka, J. L. Sessler, Y. Inokuma
J. Am. Chem. Soc. 2021, 143, 12355-12360.
TOC
14年越しの夢、ついに叶う! カルボニルひもからcalix[3]pyrroleの合成に成功。
Science誌の"In Other Journals"にてハイライトされました。
Synfactsにてハイライトされました。
プレスリリースは、こちら。   
68. Isopyrazole-Masked Tetraketone: Tautomerism and Functionalization for Fluorescent Metal Ligands
H. Shirakura, Y. Manabe, C. Kasai, Y. Inaba, M. Tsurui, Y. Kitagawa, Y. Hasegawa, T. Yoneda, Y. Ide, Y. Inokuma
Eur. J. Org. Chem. 2021, 4345–4349.
TOC
"マスク"をしたカルボニルひもで、発光性分子が出来ました。
67. Polyketone-Based Molecular Ropes as Versatile Components for Functional Materials
Y. Inokuma, Y. Inaba
Bull. Chem. Soc. Jpn. 2021, 94, 2187-2194.
TOC
カルボニルひもを使った機能性分子への展開についてAccountを発表しました。
66. Insoluble π‐Conjugated Polyimine as an Organic Adsorbent for Group 10 Metal Ions
H. Shirakura, Y. Hijikata, J. Pirillo, T. Yoneda, Y. Manabe, M. Murugavel, Y. Ide, Y. Inokuma
Eur. J. Inorg. Chem. 2021, 1705-1708.
TOC
カルボニルひもから誘導される共役ポリイミン化合物に金属吸着の性質が見つかりました。
65. Aliphatic Polyketones as Classic yet New Molecular Ropes for Structural Diversity in Organic Synthesis
Y. Inokuma, T. Yoneda, Y. Ide, S. Yoshioka
Chem. Commun., 2020, 56, 9079-9093.
TOC
カルボニルひもの概念と脂肪族ポリケトンの合成と反応性に関するFeature Articleを発表しました。
64. Spirosilicate Dimers of a Bowl-shaped Diol Generated by Intramolecular Cyclization of an Aliphatic Tetraketone Chains
Y. Inaba, Y. Inokuma
Chem. Lett. 2020, 49, 882-884.
TOC
カルボニルひもを使って加水分解に対し安定なスピロシリケートを合成しました。
63. Modular Synthesis of Oligoacetylacetones via Site-selective Silylation of Acetylacetone Derivatives
P. Sarkar, Y. Inaba, H. Shirakura, T. Yoneda, Y. Inokuma
Org. Biomol. Chem. 2020, 18, 3297-3302.
TOC
モジュール式合成により様々なシークエンスのカルボニルひもを合成しました。
62. Supramolecular Conformational Control of Aliphatic Oligoketones by Rotaxane Formation
Y. Manabe, K. Wada, Y. Baba, T. Yoneda, T. Ogoshi, Y. Inokuma
Org. Lett. 2020, 22, 3224-3228.
TOC
カルボニルひもをピラー[5]アレーンに通してロタキサンを合成しました。京大・生越研究室とのコラボレーションで生まれた成果です。
61. Chiral Monolayers with Achiral Tetrapod Molecules on Highly Oriented Pyrolytic Graphite
H. Asakawa, S. Matsui, Q. T. Trinh, H. Hirao, Y. Inokuma, T. Ogoshi, S. Tanaka, K. Komatsu, A. Ohta, T. Asakawa, T. Fukuma
J. Phys. Chem. C 2020, 124, 7760-7767.
TOC
HOPG上にテトラポッド型分子がキラル配列する現象をAFMで観測しました。さきがけ「超空間領域」メンバーの淺川先生、平尾先生、生越先生、そして、金沢大WPI Nano-LSI 福間拠点長をはじめとするメンバーとの共著論文です。
60. Polyketones as Host Materials for Solid Polymer Electrolytes
T. Eriksson, A. Mace, Y. Manabe, M. Yoshizawa-Fujita, Y. Inokuma, D. Brandell, J. Mindemark

J. Electrochem. Soc. 2020, 167, 070537.
TOC
カルボニルひもがリチウムイオン伝導材料として応用可能であることが、スウェーデン・ウプサラ大、上智大との国際共同研究により明らかとなりました。
59. Luminescent Coordination Polymers Constructed from Flexible, Tetradentate Diisopyrazole Ligand and Copper(I) Halides
T. Yoneda, C. Kasai, Y. Manabe, M. Tsurui, Y. Kitagawa, Y. Hasegawa, P. Sarkar, Y. Inokuma
Chem. Asian J. 2020, 15, 601-605.
TOC
イミンひもとハロゲン化銅(I)から発光性配位高分子を合成しました。特に、ヨウ化銅から得られた錯体は、サーモクロミズムを示しました。ICReDDの北川先生、長谷川先生との共著論文です。Front Coverに採択されました。
58. Splitting and Reorientation of π-Conjugation by an Unprecedented Photo-Rearrangement Reaction
Y. Inaba, T. Yoneda, Y. Kitagawa, K. Miyata, Y. Hasegawa, Y. Inokuma
Chem. Commun. 2020, 56, 348-351.
TOC
カルボニルひもから誘導したポリエンのπ共役を光で切断し、並べ替える新転位反応を発見しました。ICReDDの北川先生、長谷川先生、そして九大の宮田先生との共同研究論文です。Back Coverに採択されました!
57. Identification of Actinomycin D as a Specific Inhibitor of the Alternative Pathway of Peptidoglycan Biosynthesis
Y. Ogasawara, Y. Shimizu, Y. Sato, T. Yoneda, Y. Inokuma, T. Dairi
J. Antibiot. 2020, 73, 125-127.
TOC
同学科の小笠原先生、大利先生との共著論文です。Actinomycin Dの結晶構造解析をお手伝いさせて頂きました。
56. Asymmetric Synthesis of a 5,7-Fused Ring System Enabled by an Intramolecular Buchner Reaction with Chiral Rhodium Catalyst
T. Hoshi, E. Ota, Y. Inokuma, J. Yamaguchi
Org. Lett. 2019, 21, 10081-10084.
TOC
早稲田大学の山口潤一郎先生との共著論文です。不斉合成した生成物の結晶構造解析をお手伝いさせて頂きました。
55. Aliphatic Polyketones as Shapable Molecular Chains
Y. Inokuma
J. Synth. Org. Chem. Jpn. 2019, 77, 1078-1085.
TOC
カルボニルひもに関する総合論文です。
54. Two-Step Transformation of Aliphatic Polyketones into π-Conjugated Polyimines
Y. Manabe, M. Uesaka, T. Yoneda, Y. Inokuma
J. Org. Chem. 2019, 84, 9957-9964.
TOC
カルボニルひもからπ共役イミン色素の帯ができました。カバーピクチャにも採択されました。
53. Control over Coordination Self-Assembly of Flexible, Multidentate Ligands by Stepwise Metal Coordination of Isopyrazole Subunits
Y. Ashida, Y. Manabe, S. Yoshioka, T. Yoneda, Y. Inokuma
Dalton Trans. 2019, 48, 818-822.
TOC
イミンひもをパラジウムイオンとの段階的錯形成を用いて自己集合させることに成功しました。本論文に関連してInside Back Coverに採択されました。
52. Bioinspired Synthesis of Pentalene-based Chromophores from an Oligoketone Chain
Y. Saito, M. Higuchi, S. Yoshioka, H. Senboku, Y. Inokuma
Chem. Commun. 2018, 54, 6788-6791.
TOC
カルボニルひもを折り畳んで固体発光を示す色素に変換した研究です。
51. Oligoacetylacetones as Shapable Carbon Chains and Their Transformation to Oligoimines for Construction of Metal-organic Architectures
M. Uesaka, Y. Saito, S. Yoshioka, Y. Domoto, M. Fujita, Y. Inokuma
Communications Chemistry 2018, 1, Article Number 23.
TOC
カルボニルひも化合物のコンセプト、合成、分子集合体への応用を報告した猪熊グループ初の論文です。
北海道大学のプレスリリースは、こちら。 JST版は、こちら。
Behind the Paper (Nature Research Chemistry Community)の紹介記事
50. Chiral Crystalline Sponges for the Absolute Structure Determination of Chiral Guests
K. Yan, R. Dubey, T. Arai, Y. Inokuma, M. Fujita
J. Am. Chem. Soc. 2017, 139, 11341-11344.
49. Structural Elucidation of Trace Amounts of Volatile Compounds Using the Crystalline Sponge Method
N. Zigon, T. Kikuchi, J. Ariyoshi, Y. Inokuma, M. Fujita
Chem. Asian J. 2017, 12, 1057-1061.
48. Finding a New Crystalline Sponge from a Crystallographic Database
Y. Inokuma, K. Matsumura, S. Yoshioka, M. Fujita
Chem. Asian. J. 2017, 12, 208-211. (Front Cover)
47. X-ray Structure Analysis of Ozonides by the Crystalline Sponge Method
S. Yoshioka, Y. Inokuma, V. Duplan, R. Dubey, M. Fujita
J. Am. Chem. Soc. 2016, 138, 10140-10142.
46. A Saccharide-based Crystalline Sponge for Hydrophilic Guests
G.-H. Ning, K. Matsumura, Y. Inokuma, M. Fujita
Chem. Commun. 2016, 52, 7013-7015.
45. Structure Determination of Microbial Metabolites by the Crystalline Sponge Method
Y. Inokuma, T. Ukegawa, M. Hoshino, M. Fujita
Chem. Sci. 2016, 7, 3910-3913.
44. The Crystalline Sponge Method Updated
M. Hoshino, A. Khutia, H. Xing, Y. Inokuma, M. Fujita
IUCrJ 2016, 3, 139-151.
43. Where is the Oxygen? Structural Analysis of a-Humulene Oxidation Products by the Crystalline Sponge Method
N. Zigon, M. Hoshino, S. Yoshioka, Y. Inokuma, M. Fujita
Angew. Chem. Int. Ed. 2015, 54, 9033-9037.
42. Absolute Structure Determination of Compounds with Axial and Planar Chirality Using the Crystalline Sponge Method
S. Yoshioka, Y. Inokuma, M. Hoshino, T. Sato, M. Fujita
Chem. Sci. 2015, 6, 3765-3768.
41. Networked-Cage Microcrystals for Evaluation of Host-guest Interactions
S. Matsuzaki, T. Arai, K. Ikemoto, Y. Inokuma, M. Fujita
J. Am. Chem. Soc. 2014, 136, 17899-17901.
40. Visualization of Solution Chemistry by X-ray Crystallography Using Porous Coordination Networks
Y. Inokuma, M. Fujita
Bull. Chem. Soc. Jpn. 2014, 87, 1161-1176.
(Award Article, Back Cover)
39. Radical C-H Functionalization of Heteroarenes under Electrochemical Control
A. O'Brien, A. Maruyama, Y. Inokuma, M. Fujita, P. S. Baran, D. G. Blackmond
Angew. Chem. Int. Ed. 2014, 53, 11868-11871.
(Selected as a Hot Paper)
38. X-ray Snapshot Observation of Palladium-Mediated Aromatic Bromination in a Porous Complex
K. Ikemoto, Y. Inokuma, K. Rissanen, M. Fujita
J. Am. Chem. Soc. 2014, 136, 6892-6895.
(Highlighted by "Chemistry World", RSC)
37. Preparation and Guest-uptake Protocol for a Porous Complex Useful for 'Crystal-free' Crystallography
Y. Inokuma, S. Yoshioka, J. Ariyoshi, T. Arai, M. Fujita
Nature Protocols 2014, 9, 246-252.
36. Stable Encapsulation of Acrylate Esters in Networked Molecular Capsules
G.-H Ning, Y. Inokuma, M. Fujita
Chem. Asian J. 2014, 9, 466-468.
(VIP paper, Inside Cover)
35. Unique Ultrafast Energy Transfer in a Series of Phenylene-bridged Subporphyrin-porphyrin Hybrids
J. Oh, J. Sung, M. Kitano, Y. Inokuma, A. Osuka, D. Kim
Chem. Commun. 2014, 50, 10424-10426.
34. Dynamic Behavior of M6L4 Capsules in Solution and Crystalline States
G.-H Ning, Y. Inokuma, M. Fujita
Chem. Asian J. 2013, 8, 2596-2599.
33. X-ray analysis on the nanogram to microgram scale using porous complexes
Y. Inokuma, S. Yoshioka, J. Ariyoshi, T. Arai, Y. Hitora, K. Takada, S. Matsunaga, K. Rissanen, M. Fujita
Nature 2013, 495, 461-466.
(Highlighted by "Nature news and views" )
(Highlighted by "C&EN", ACS)
(Highlighted by "Chemistry World", RSC)
32. Reagent-Installed Capsule Network: Selective Thiocarbamoylation of Aromatic Amines in Crystals with Pre-installed CH3NCS
Y. Inokuma, G.-H. Ning, M. Fujita
Angew. Chem. Int. Ed. 2012, 51, 2379-2381.
31. Oxocyclohexadienylidene-Substituted Subporphyrins
S. Hayashi, J. Sung, Y. Sung, Y. M. Sung, Y. Inokuma, D. Kim, A. Osuka
Angew. Chem. Int. Ed. 2011, 50, 3253-3256.
30. Bimolecular Reaction via the Successive Introduction of Two Substrates into the Crystals of Networked Molecular Cages
Y. Inokuma, N. Kojima, T. Arai, M. Fujita
J. Am. Chem. Soc. 2011, 133, 19691-19693.
29. Diels-Alder via Molecular Recognition in a Crystalline Molecular Flask
K. Ikemoto, Y. Inokuma, M. Fujita
J. Am. Chem. Soc. 2011, 133, 16806-16808.
28. Shedding Light on Hidden Reaction Pathways in Radical Polymerization by a Porous Coordination Network
Y. Inokuma, S. Nishiguchi, K. Ikemoto, M. Fujita
Chem. Commun. 2011, 47, 12113-12115.
27. Synthesis and Properties of Boron(III)-Coordinated Subbacteriochlorins
S. Hayashi, E. Tsurumaki, Y. Inokuma, P. Kim, Y. M. Sung, D. Kim, A. Osuka
J. Am. Chem. Soc. 2011, 133, 4254-4256.
26. Crystalline Molecular Flasks
Y. Inokuma, M. Kawano, M. Fujita
Nature Chem. 2011, 3, 349-358.
25. A Molecular Capsule Network: Guest Encapsulation and Control of Diels-Alder Reactivity
Y. Inokuma, S. Yoshioka, M. Fujita
Angew. Chem. Int. Ed. 2010, 49, 8912-8914.
24. Networked Molecular Cages as Crystalline Sponges for Fullerenes and Other Guests
Y. Inokuma, T. Arai, M. Fujita
Nature Chem. 2010, 2, 780-783.
(Highlighted by "C&EN", ACS)
23. The Reaction of Organozinc Compounds with an Aldehyde within a Crystalline Molecular Flask
K. Ikemoto, Y. Inokuma, M. Fujita
Angew. Chem. Int. Ed. 2010, 49, 5750-5752.
22. The Catalytic Z to E Isomerization of Stilbenes in a Photosensitizing Porous Coordination Network
K. Ohara, Y. Inokuma, M. Fujita
Angew. Chem. Int. Ed. 2010, 49, 5507-5509.
21. Regioselective Huisgen Cycloaddition within Porous Coordination Networks
T. Kawamichi, Y. Inokuma, M. Fujita
Angew. Chem. Int. Ed. 2010, 49, 2375-2377.
(Highlighted by "Noteworthy Chemistry", ACS)
20. A Porous Coordination Network Catalyzes an Olefin Isomerization Reaction in the Pore
K. Ohara, M. Kawano, Y. Inokuma, M. Fujita
J. Am. Chem. Soc. 2010, 132, 30-31.
19. meso-Tris(oligo-2,5-thienylene)-Substituted Subporphyrins
S. Hayashi, Y. Inokuma, A. Osuka
Org. Lett. 2010, 12, 4148-4151.
18. meso-Trifluoromethyl-substituted Subporphyrin from Ring-splitting Reaction of meso-Trifluoromethyl-substituted [32]Heptaphyrin(1.1.1.1.1.1.1)
R. Sakamoto, S. Saito, S. Shimizu, Y. Inokuma, N. Aratani, A. Osuka
Chem. Lett. 2010, 39, 439-441.
17. meso-Trialkyl-substituted Subporphyrins
S. Hayashi, Y. Inokuma, S. Easwaramoorthi, K. S. Kim, D. Kim, A. Osuka
Angew. Chem. Int. Ed. 2010, 49, 321-324.
16. Versatile Photophysical Properties of meso-Aryl Substituted Subporphyrins: Dipolar and Octupolar Charge-Transfer Interactions
S. Easwaramoorthi, J.-Y. Shin, S. Cho, P. Kim, Y. Inokuma, E. Tsurumaki, A. Osuka, D. Kim
Chem. Eur. J. 2009, 15, 12005-12017.
15. Capped Subporphyrins
Y. Inokuma, A. Osuka
Chem. Eur. J. 2009, 15, 6863-6876.
14. 1,4-Phenylene-bridged Subporphyrin-porphyrin Dyad, Triad, and Tetrad
Y. Inokuma, S. Hayashi, A. Osuka
Chem. Lett. 2009, 38, 206-207.
13. Peripheral Hexabromination, Hexaphenylation, and Hexaethynylation of meso-Aryl- Substituted Subporphyrins
E. Tsurumaki, Y. Inokuma, S. Easwaramoorthi, J. M. Lim, D. Kim, A. Osuka
Chem. Eur. J. 2009, 15, 237-247.
12. 3,3- and 4,4-Biphenylene-Bridged Subporphyrin Dimers
Y. Inokuma, A. Osuka
Org. Lett. 2008, 10, 5561-5564.
11. Unambiguous Identification of Möbius Aromaticity for meso-Aryl-Substituted [28]Hexaphyrins(1.1.1.1.1.1)
J. Sankar, S. Mori, S. Saito, H. Rath, M. Suzuki, Y. Inokuma, H. Shinokubo, K. S. Kim, Z. S. Yoon, J.-Y. Shin, J. M. Lim, Y. Matsuzaki, O. Matsushita, A. Muranaka, N. Kobayashi, D. Kim A. Osuka
J. Am. Chem. Soc. 2008, 130, 13568-13579.
10. meso-(4-(N,N-Dialkylamino)phenyl)-Substituted Subporphyrins: Remarkably Perturbed Absorption Spectra and Enhanced Fluorescence by Intramolecular Charge Transfer Interactions
Y. Inokuma, S. Easwaramoorthi, Z. S. Yoon, D. Kim, A. Osuka
J. Am. Chem. Soc. 2008, 130, 12234-12235.
9. Effective Expansion of the Subporphyrin Chromophore Through Conjugation with meso-Oligo(1,4-phenyleneethynylene) Substituents: Octupolar Effect on Two-Photon Absorption
Y. Inokuma, S. Easwaramoorthi, S. Y. Jang, K. S. Kim, D. Kim, A. Osuka
Angew. Chem. Int. Ed. 2008, 47, 4840-4843.
8. Subporphyrins: Emerging Contracted Porphyrins with Aromatic 14π-Electronic Systems and Bowl-Shaped Structures: Rational and Unexpected Synthetic Routes
Y. Inokuma, A. Osuka
Dalton Trans. 2008, 2517-2526. (Perspective, Front Cover)
7. Synthesis and Characterization of meso-Aryl-Substituted Subchlorins
E. Tsurumaki, S. Saito, K. S. Kim, J. M. Lim, Y. Inokuma, D. Kim, A. Osuka
J. Am. Chem. Soc. 2008, 130, 438-439.
6. Complementary Face-to-Face Dimer Formation From meso-Aryl Subporphyrins Bearing a 2-Carboxyphenyl Group
Y. Inokuma, A. Osuka
Chem. Commun. 2007, 2938-2940.
5. meso-Aryl-Substituted Subporphyrins: Synthesis, Structures, and Large Substituent Effects on Their Electronic Properties
Y. Inokuma, Z. S. Yoon, D. Kim, A. Osuka
J. Am. Chem. Soc. 2007, 129, 4747-4761.
4. Tribenzosubporphines: Synthesis and Characterization
Y. Inokuma, J. H. Kwon, T. K. Ahn, M.-C. Yoon, D. Kim, A. Osuka
Angew. Chem. Int. Ed. 2006, 45, 961-964.
3. Enlarged π-Electronic Network of a meso-meso, β-β, β-β Triply Linked Dibenzoporphyrin Dimer that Exhibits a Large Two-Photon Absorption Cross Section
Y. Inokuma, N. Ono, H. Uno, D. Y. Kim, S. B. Noh, D. Kim, A. Osuka
Chem. Commun. 2005, 3782-3784.
2. A Doubly N-Fused Benzohexaphyrin and Its Rearrangement to a Fluorescent Macrocycle upon DDQ Oxidation
Y. Inokuma, T. Matsunari, N. Ono, H. Uno, A. Osuka
Angew. Chem. Int. Ed. 2005, 44, 1856-1860.
1. meso-Porphyrinyl-Substituted Porphyrin and Expanded Porphyrins
Y. Inokuma, A. Osuka
Org. Lett. 2004, 6, 3663-3666.